一锅法 Barbier 聚合制备含有机磷簇发光高分子，兼具聚集诱导发光与光致变色
研究报道了一种 Barbier 聚合诱导发光策略，通过一锅法同步形成 C–C 和 C–P 键，制备出含有机磷的刺激响应簇发光高分子，该材料具有聚集诱导发光和光致变色特性。文中还展示了其作为镍催化 Kumada 反应的高效聚合物配体以及刺激响应颜料的用途。
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推荐理由：原文用一锅法 Barbier 聚合同步构建 C–C 与 C–P 键，为刺激响应簇发光高分子提供了一条简化合成路线。
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合成方法 最新动态
把高分子做出来的新办法：聚合方法、催化与引发体系、单体与交联剂设计、拓扑结构设计与新的加工路线。
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