Organic Letters·· 10 小时前AI 评分42
机械化学脱羧自由基偶联制备非端基S-和C-糖苷
Mechanochemical Decarboxylative Radical Couplings toward Nonanomeric S- and C- Glycosides
AI 导读
一种无催化剂、无光照的一锅两步机械化学脱羧官能化方法，以Hantzsch酯与锌粉为复合还原体系生成糖基自由基，再被多种自由基受体捕获，用于组装非端基S-和C-糖苷。该方案底物适用范围广，并给出优异的立体选择性。
图表、补充材料与最终表述以原文为准。阅读原文
来源：Organic Letters · doi.org
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