Organic Letters·· 11 小时前AI 评分47
光氧化还原/钴催化糖烯的立体选择性2-脱氧糖基化：MHAT-RPC策略与C/N/O亲核试剂
Photoredox/Cobalt-Catalyzed Stereoselective 2-Deoxyglycosylation of Glycals via MHAT-RPC with C/N/O-Nucleophiles
AI 导读
光氧化还原与钴协同催化的MHAT及亲核胺化策略，实现了糖烯与简单路易斯碱性苯胺的直接2-脱氧糖基化，以良好至优异收率合成多种β-N-糖苷。该方法同样适用于酚、醇和吲哚，均表现出优异的立体选择性，为2-脱氧糖苷及糖苷类治疗药物的立体选择性合成提供了新平台。
图表、补充材料与最终表述以原文为准。阅读原文
来源：Organic Letters · doi.org
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