Journal of the American Chemical Society·· 10 小时前AI 评分36
吡咯–吡啶嵌入的碗烯（buckybowl）TAHS：合成及其用于芥子气快速成像
A Pyrrole–Pyridine-Embedded Buckybowl: Synthesis and Application for Rapid Sulfur Mustard Imaging
AI 导读
研究通过“扭曲前体→缺口浅碗→深碗”策略合成吡咯/吡啶嵌入的碗烯三氮杂高苏曼烯（TAHS），以逐步累积高应变能。TAHS 呈现高度酸敏感光物理性质，亚化学计量质子化即引起 Δλmax = 110 nm 的红移与显著荧光增强。该化合物可作为芥子气荧光探针，响应时间 5 s、LOD < 100 nM，并实现活细胞与小鼠成像。
图表、补充材料与最终表述以原文为准。阅读原文
来源：Journal of the American Chemical Society · doi.org
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