Macromolecules·· 9 天前AI 评分50
叠氮端基聚(烷氧羰基亚甲基)的合成：2-溴乙醇介导重氮乙酸酯链转移聚合及后续叠氮化用于 click chemistry
Azide-Capped Poly(alkoxycarbonylmethylene)s for Click Chemistry: Their Syntheses by 2-Bromoethanol-Mediated Chain Transfer Polymerization of Diazoacetate Followed by Azidation
AI 导读
以π-allylPdCl(Py)为引发剂、2-溴乙醇为链转移剂（CTA）聚合重氮乙酸酯，制得Br端基聚(烷氧羰基亚甲基)（PACM），再经四丁基叠氮化铵（TBAAZ）亲核取代得到N3端基PACM，MALDI-TOF-MS确认两步转化高效进行。
来源：Macromolecules · doi.org