Small·· 2 天前AI 评分36
通过预成型节点与机器学习辅助合成控制 Zr 基 MOF 的晶型与粒径
Controlling Polymorphism and Particle Size in Zr‐Based Metal‐Organic Frameworks Through Preformed Nodes and Machine‐Learning‐Assisted Synthesis
AI 导读
以预成型 Zr6-oxo 簇为节点，系统调控调节剂种类与用量、共调节剂、配体当量、温度和稀释度，在 NU-1000 与 NU-901 两种同簇同配体、拓扑不同的 Zr 基 MOF 上实现从 <100 nm 到约 1 µm 的多个粒径区间。机器学习分析定量区分了影响相选择与粒径演化的多变量因素，使合成参数空间可预测导航，为晶型与生长控制提供可复现的实验-计算工作流。
图表、补充材料与最终表述以原文为准。阅读原文
来源：Small · doi.org
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