Journal of the American Chemical Society·· 14 小时前AI 评分42
12-连接配体异构调控MOF拓扑：MOF-1300与MOF-1400的网状合成
Programming MOF Topology through Twelve-Connected Linker Isomerism
AI 导读
通过12-连接配体m/p-HBC-LH12的间位与对位羧基取代差异，分别合成出两种12-连接纳米石墨烯基锆MOF：间位异构体引导8-连接立方Zr簇组装，得到具有三节点(3,6,8)-c rcb1新拓扑的MOF-1300；对位异构体则使Zr簇呈12-连接六方棱柱几何，得到罕见的(3,6,12)-c kex拓扑MOF-1400。
图表、补充材料与最终表述以原文为准。阅读原文
来源：Journal of the American Chemical Society · doi.org
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