Journal of the American Chemical Society·· 1 天前精选AI 评分62
水相催化活性 ROMP：亚化学计量 Ru 配合物合成热响应聚合物与 PEG 嵌段共聚物
Catalytic Living Ring-Opening Metathesis Polymerization in Aqueous Media: A Route to Sustainable and Thermoresponsive Polymers
AI 导读
研究报道了一种在水相中进行的催化活性开环易位聚合（ROMP）方法，可在 pH 2 的水中或含 0.1 M NaCl 的 9:1 水/THF 混合体系中，用亚化学计量 Ru 配合物合成结构明确的 ROMP 聚合物。
推荐理由
在 pH 2 水相或水/THF 混合体系中用亚化学计量 Ru 配合物实现活性 ROMP，并保留链端官能度以做蛋白偶联。
创新点
用亚化学计量 Ru 配合物在水相实现活性 ROMP，并保住链端官能度，使水相 ROMP 能直接做蛋白偶联和 PEG 嵌段共聚物。
图表、补充材料与最终表述以原文为准。阅读原文
来源：Journal of the American Chemical Society · doi.org
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