Macromolecules·· 10 小时前AI 评分28
温度对离子液体溶液中Pluronic嵌段共聚物两亲性的影响：密度泛函理论研究
Effects of Temperature on Amphiphilicity of Pluronic Block Copolymers in Ionic Liquid Solutions Studied with Density Functional Theory
AI 导读
密度泛函理论结合温度依赖热力学分析量化了离子液体离子、水与Pluronic嵌段共聚物链段间的成对结合自由能，揭示聚合物-水与离子-水缔合对温度具有强熵敏感性，而聚合物-聚合物与离子-聚合物接触相对稳定。阳离子在PEO与PPO链段间的选择性结合进一步调节这一平衡，为解释不同离子液体改变云点与胶束化行为提供了热力学框架。
图表、补充材料与最终表述以原文为准。阅读原文
来源：Macromolecules · doi.org
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