Journal of the American Chemical Society·· 11 小时前AI 评分38
胶束作为受限液体：表面活性剂胶束中溶质旋转的标准与二维动力学
Micelles as a Confined Liquid: Standard and Two-Dimensional Kinetics of Solute Rotation in Surfactant Micelles
AI 导读
表面活性剂胶束内溶质旋转的受限效应主要源于胶束中心而非表面，与强链有序模型不符。改变溶质表明，受限导致的减速大多发生在胶束中心；二维动力学显示速率分散主要来自不同溶质分子间的速率异质性，并识别出与烃链构象弛豫耦合的均相组分。胶束呈无结构状态，受限效应源于烃链长度与颗粒直径的不匹配，而非表面效应。
图表、补充材料与最终表述以原文为准。阅读原文
来源：Journal of the American Chemical Society · doi.org
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